Phenylcarbamate-Modified Paper for Paper Chromatographic Analysis of Hydrophobic Compounds

نویسندگان

چکیده

Paper chromatography is a low-cost and facile analytical method traditionally used to analyze hydrophilic substances. For the application substances with lower polarity, we prepared stationary phase based on filter paper modified phenyl isocyanate (PI-FP), bearing carbamate moieties for hydrophobic, π-π, electrostatic interactions. The preparation chromatographic methods were established by selecting papers, comparing different chemical structures, optimizing modification procedure, investigating eluents, quantitatively parameterizing separation behavior character of analytes. PI-FP exhibited better performance than esterified FPs enabled analysis various dyes both positive negative clogP (calculated water-octanol partition coefficient). We also demonstrated an this system preparative using thread-like PI.

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ژورنال

عنوان ژورنال: Technologies (Basel)

سال: 2022

ISSN: ['2227-7080']

DOI: https://doi.org/10.3390/technologies11010001